Quasi-critical condition to balance the scaling and membrane lifespan tradeoff in hypersaline water concentration

Abstract

Mineral scaling is an inconvenient obstacle for membrane distillation in hypersaline wastewater concentration applications, compromising membrane lifespan to maintain high water recovery. Although various measures are devoted to alleviating mineral scaling, the uncertainty and complexity of scale characteristics make it difficult to accurately identify and effectively prevent. Herein, we systematically elucidate a practically applicable principle to balance the trade-off between mineral scaling and membrane lifespan. Through experimental demonstration and mechanism analysis, we find a consistent concentration phenomenon of hypersaline concentration in different situations. Based on the characteristics of the binding force between the primary scale crystal and the membrane, the quasi-critical concentration condition is sought to prevent the accumulation and intrusion of mineral scale. The quasi-critical condition achieves the maximum water flux on the premise of guaranteeing the membrane tolerance, and the membrane performance can be restored by undamaged physical cleaning. This report opens up an informative horizon for circumventing the inexplicable scaling explorations and develops a universal evaluation strategy to provide technical support for membrane desalination.