Abstract

A master equation is derived to describe quantum systems connected to dynamically-evolving mesoscopic baths, progressing towards the control of nanoscale quantum technologies such as engines and refrigerators.

Highlights

  • To understand the potential of future quantum technologies, it is essential to develop an efficient description of microscopic systems far from equilibrium

  • We show that the extended microcanonical master equation” (EMME) does provide an efficient way to describe the non-Markovian dynamics of open quantum systems but it connects to a plethora of actively discussed topics in nonequilibrium statistical mechanics

  • V, we introduce a consistent nonequilibrium thermodynamic framework that includes slowly driven systems

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Summary

INTRODUCTION

To understand the potential of future quantum technologies, it is essential to develop an efficient description of microscopic systems far from equilibrium. Quantum master equations are an important tool to describe the nonequilibrium dynamics of small systems in contact with an external environment [1,2,3]. Master equations have the advantage that they apply to a large class of open systems, are intuitive, and often allow further analytical progress in the description. The idea is to keep track of the bath dynamics at a coarse-grained level and include to some degree system-bath correlations This approach was previously formalized using correlated projection operator techniques [5,6,7,8] and it has been shown to significantly improve standard perturbative master equations [6,8,9,10]. To keep the presentation focused, generalizations and additional results are shifted to the Appendixes

General idea and final result
Detailed derivation
Heuristic approach
Random matrix coupling with a dense environment
The eigenstate thermalization hypothesis
Strict energy conservation
Equilibrium states and local detailed balance
System-bath correlations
EXAMPLE
NONEQUILIBRIUM THERMODYNAMICS
The first law of thermodynamics
The second law of thermodynamics
Connecting the first and second law
Testing the results numerically
GENERALIZATION TO MULTIPLE ENVIRONMENTS
OUTLOOK AND COMPARISON WITH OTHER MASTER EQUATIONS
Details of the heuristic approach
Details of the RMT approach We consider bath coupling operators of the form
Details of the ETH approach
Connection between the three approaches
Positivity
Symmetry
Additive structure
Energy conservation
Steady state
Full Text
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