Abstract
Quantum-mechanical evolution in a slowly varying double-well potential is analyzed in the semiclassical limit to determine the transition probability due to loss of adiabatic invariance of states having energy close to that of a separatrix in the equivalent classical system. Transformation to the rotating-axis basis reduces the problem to the integration of a set of coupled differential equations. In the adiabatic limit the integration is carried out by the method of successive approximations. For adiabatic parameter \ensuremath{\epsilon} of the order of the inverse, 1/N, of the number of quantum states with energy below the separatrix, the spread of the quantum adiabatic invariant is exponentially small in the inverse of the adiabaticity parameter. Surprisingly, the transition to this quantum adiabatic behavior occurs far below the minimum transition frequency of the system.
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