Abstract

In this study, we conduct quantum dynamical calculations at relatively high energies on the exchange reaction 15N ＋ 14N14N →15N14N ＋ 14N on its ground electronic N3 (4A′′) potential energy surface (PES) utilizing the time-dependent wave packet (TDWP) propagation method. Our primary focus is on analyzing the reaction mechanism for 15N ＋ ortho-14N14N (j = 0) and para-14N14N (j = 1) cases. We also explore the influence of varying J (up to 120) of the three-body system and the initial vibrational level (ν = 1, 5, 10) of the diatom on the reaction probability (RP) for ortho and para configurations.

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