​Quantitative assessment of heavy metal concentrations, pollution levels, and sources apportionment in one of China's top 10 most livable cities.

Abstract

Urban topsoil is not only an essential part of the urban ecosystem, but also a powerful carrier of pollutants in the urban environment. In this paper, 130 topsoil samples from urban area of Xinyang in central-eastern China were selected, the aim is to quantitatively investigate the concentrations, pollution levels, and sources apportionment of 8 heavy metals (HMs, encompassing arsenic (As), cobalt (Co), copper (Cu), chromium (Cr), lead (Pb), nickel (Ni), vanadium (V), and zinc (Zn)) via geochemical method. The main conclusions are as follows. (1) The eight HMs in the topsoil have been artificially enriched to varying degrees, which are lower than the street dust levels sampled in pairs. (2) Cu, Zn, and Pb were significantly contaminated, and As, Co, Ni, Cr, and V were relatively low levels of contamination. Overall, comprehensive pollution levels were particularly severe, with 30.0%, 39.2%, and 30.8% for slight, moderate, and serious pollution, respectively. (3) Co, Ni, V, and Cr predominantly originated from natural sources, the percentage contribution of which is 6.3%; Pb, As, Cu, and Zn were predominantly derived from traffic-derived sources, with a percentage contribution of 93.7%. Thus, the first-order source of HMs in the topsoil originates from traffic-induced activities, similar to the case of street dust. Our findings can be beneficial in providing local governments with a reference to formulate environmental pollution controls, and also provide a case study for environmental pollution control in the other livable cities in China.