Quality Assessment Statistic Evaluation of X-Ray Fluorescence via NIST and IAEA Standard Reference Materials

O M H Ahmed,Ftihia Seedig,A M Salih,A M Mustafa,E M A Mohamed,Farouk I Habbani

doi:10.4236/wjnst.2017.72010

Abstract

The aim of this study is a quality assessment of X-ray fluorescence laboratory located at the University of Khartoum. The X-ray fluorescence spectrometer system consists, a set of three 109Cd sources of an initial nominal activity of 10 μCi, and Si(Li) detector Energy Dispersive XRF(EDXRF) systems. It is important to carry out this work because it has an effective contribution for a wide range of research and services. The assessment was carried out by measuring 8 NIST-2709a (soil) and 13 IAEA-155 (milk powder) standard reference material samples for repeatability examinations to test the measurement precision. The total combined standards uncertainty values for XRF lab were estimated by an error from repeatability measurements adding 2.6% for error propagation related to the method. For accuracy assessment, three standard statistic approaches were applied, i.e. the Bias %, zeta-score, and En-number. The bias of all elements for both standard materials was found to be within a deviation range from −28% to 7.8%. The results of all elements for both the zeta-score test and En-number have satisfactory results except Th (Thorium) and Zr (Zirconium) which consider as questionable results for NIST SRM 2709a and unsatisfactory results for En-number.

Highlights

IntroductionH. Ahmed et al 122 nondestructive instrumental method for qualitative and quantitative analysis of chemical elements [1]
The total combined standards uncertainty values for X-ray fluorescence analysis (XRF) lab were estimated by an error from repeatability measurements adding 2.6% for error propagation related to the method
The results of all elements for both the zeta-score test and En-number have satisfactory results except Th (Thorium) and Zr (Zirconium) which consider as questionable results for NIST Standard Reference Materials (SRMs) 2709a and unsatisfactory results for En-number

Summary

Introduction

H. Ahmed et al 122 nondestructive instrumental method for qualitative and quantitative analysis of chemical elements [1]. Ahmed et al 122 nondestructive instrumental method for qualitative and quantitative analysis of chemical elements [1] It is based on measurements of energies and intensities of the X-ray spectral lines emitted by secondary excitation of the elements of interest. The primary beam of photons from an X-ray source strikes the specimen (sample or standard). The absorption of these photons by photoelectric effect produces vacancies in the inner electron shells of the atoms of the material. Electrons from the outer shells transfer to fill these vacancies, followed by the emission of secondary spectral lines having characteristic energies of the element (the basis of qualitative analysis), and intensities related to its concentrations [2]

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