Abstract
Polypyrrole (PPy) nanofibers loaded with either palladium (II) acetate (PPy/Pd(O 2CCH 3) 2) or palladium (II) nitrate (PPy/Pd(NO 3) 2) were characterized by TEM, SEM, EDX, Raman and FTIR techniques prior to their use as sensing materials for QCM based mercury vapor sensors. The QCM based sensor loaded with PPy/Pd(O 2CCH 3) 2 nanofibers was observed to perform better over that of the PPy/Pd(NO 3) 2 loaded QCM and is postulated to be due to the lack of Pd salt reduction in the PPy/Pd(O 2CCH 3) 2 matrix. The developed sensor was observed to operate with a response precision of ±5% over a 16 h testing period, and can withstand the presence of different levels of humidity at an operating temperature of 28 °C. Furthermore, the PPy/Pd(O 2CCH 3) 2 based sensor was found to have a response time ( t 90) of ∼45 min towards a Hg vapor concentration of 10.55 mg/m 3 balanced in either dry nitrogen or in streams containing up to 38% RH at near room temperature (28 °C). The stability of the developed sensor over 50 h of continuous testing towards Hg vapor under varying humidity levels indicates that a PPy/Pd(O 2CCH 3) 2 thin layer is a good choice for near room temperature Hg vapor sensing applications.
Published Version
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