Abstract

Developing a high energy density supercapacitor is of great challenge due to the low surface area of commercial activated carbon. The present work aims at developing highly porous nitrogen-doped porous carbon from biomass for supercapacitors. Herein, Mesua ferrea (Nahor) shells, a widely available biomass in northeast India, was used to prepare porous carbon. The effect of activation temperature on structural, textural properties, and electrochemical performance is studied. The carbonization temperature highly influenced the pore structure, porosity, surface area, and thereby influencing the electrochemical performance. The porous carbon pyrolyzed at 700 °C delivered a high specific capacitance of 210 F g-1 at 1 A g-1, higher than porous carbon made at higher temperature (27.5 F g-1 at 1 A g-1 for carbon pyrolyzed at 800 °C). The results provide insights that will be of use in the development of high-energy-density capacitors employing biomass-derived porous carbon.

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