Pyrolysis features of Dracaena draco lignocellulosic fibers: Kinetic and thermodynamic analysis at various heating rates through coats-redfern method

Abstract

This study evaluated the thermokinetic and thermodynamic properties of Dracaena draco fibers (DDFs) through thermogravimetric analysis (TGA). The DDFs underwent non-isothermal heating in a nitrogen atmosphere, with 5, 10, and 20 °C/min heating rates starting at 20 °C and reaching 800 °C. TGA analysis demonstrated that the pyrolysis of DDFs took place in three clearly defined phases: dehydration, devolatilization, and solid biochar. The thermokinetic and thermodynamic properties were computed for the devolatilization phase of mass reduction. The Coats-Redfern technique employed twenty-one separate kinetic equations derived from four fundamental solid-state reaction processes. Out of all the diffusivity models (DMs), the Ginstlinge-Brounshtein (DM5), Jander (3D diffusion) (DM7), and Ginstling models (DM8) had the best fit, as indicated by their highest coefficient of regression values (R2 > 0.990) across all the three heating rates. The activation energy values found by the DM5, DM7, and DM8 models are 76.5, 82.32, and 76.47 kJ/mol, respectively, for the 5 °C/min heating rate. The thermodynamic variables, including the entropy, free energy, and enthalpy change, were calculated based on the kinetic data. The study’s findings are significant for evaluating the DDFs' potential as an energy source, constructing reactors, producing chemicals, and understanding the DDFs’s features for composite synthesis.