Abstract
The role of bi- and ter-dentate pyridylthioether ligands in palladium and platinum coordination and organometallic chemistry is discussed. The binding ability of these ligands concerning the proton, copper and palladium is revisited. Moreover, the reactivity imparted by these ligands to several types of metal complexes in low and high oxidation states is examined. The complexes and the reactions explored are (i) allyl derivatives with respect to allyl amination (ii) olefin complexes and olefin exchange equilibrium reactions (iii) methyl derivatives and reactions of allene insertion. The synthesis of pyridylthioether-based dendrimers is also taken into account together with their solution behaviour when used as ancillary ligands in allyl metallo-dendrimer derivatives when the allylamination reactions are considered.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
