Abstract
1. Using pulsed radiolysis the authors have investigated the products of one-electron reduction of P2W18O 62 6− and P2W17O 61 10− ions in neutral aqueous solutions. They have determined their optical characteristics and the rate constants of formation. 2. The reaction of hydrogen atoms with P2W18O 62 6− in acid aqueous solutions leads to formation of [P2W18O62·H]6−. 3. They have established that ionizing radiation stimulates hydrolysis of heteropoly compounds; a mechanism of the process has been proposed.
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