Pt–TiO2–Nb2O5 heterojunction as effective photocatalyst for the degradation of diclofenac and ketoprofen

Abstract

Pt–TiO2–Nb2O5 heterojunction was synthetized and studied for the photocatalytic removal of diclofenac (DCF) and ketoprofen (KTF) under UV light irradiation. The physical-chemical properties of the prepared catalysts were analysed by different characterization techniques revealing that the lowest platinum nanoparticle size and the better metal distribution was observed in Pt–TiO2–Nb2O5 sample. The Pt–TiO2–Nb2O5 heterojunction possessed the best photocatalytic activity toward both the photodegradation and mineralization of the two selected pollutants. The optimal photocatalyst showed a DCF and KTF mineralization rate of 0.0555 and 0.0746 min−1, respectively, which were higher than those of Pt–TiO2 (0.0321 min−1 for DCF and 0.0597 min−1 for KTF). The experiments driven to analyse the effects of free radical capture showed that ·OH, ·O2− and h+ have a primary role in reactive during the photocatalytic reaction. The improved photocatalytic performances of the Pt–TiO2–Nb2O5 heterojunction could be argue by a direct Z-scheme mechanism in which the Pt0 nanoparticles could act as a bridge between TiO2 and Nb2O5, improving the electron-hole separation and, ultimately, enhancing the photocatalytic removal rate of both DCF and KTF.