Prospects of industrial membrane concentrates: treatment of landfill leachates by coupling reverse osmosis and wet air oxidation.

Abstract

Stabilized landfill leachates are characterized by a high chemical oxygen demand and limited biodegradability. This study investigates the removal of the organic fraction (chemical oxygen demand and total organic carbon) using a treatment approach that couples membrane processes and wet air oxidation (operating at 200-300 °C and 18 MPa). The aim is to address the challenges posed by landfill leachate membrane concentrates considering variations throughout the year across three different seasons. The efficiency of the treatment path was assessed through the removal of the chemical oxygen demand and total organic carbon, with additional insights provided by fluorescence spectroscopy to evaluate the degradation of the organic compounds' complexity. The most favorable results were achieved at the highest temperature (300 °C) with removals over 90% for total organic carbon and 87% for chemical oxygen demand, along with a complete elimination of fluorescence. The coupling of membrane processes and wet air oxidation has demonstrated its effectiveness in degrading the organic compounds of landfill leachates. The overall mass balance on the treatment path indicates the feasibility of discharging the treated effluent into the environment, meeting regulatory thresholds for total organic carbon and chemical oxygen concentrations.