Properties of Star‐Branched Polymer Chains Near a Surface

Abstract

AbstractWe considered two model systems of star‐branched polymers near an impenetrable surface. The model chains were constructed on a simple cubic lattice. Each star polymer consisted of f = 3 arms of equal length and the total number of segments was up to 799. The excluded volume effect was included into these models only and therefore the system was studied at good solvent conditions. In the first model system polymer chain was terminally attached with one arm to the surface. The grafted arm could slide along the surface. In the second system the star‐branched chain was adsorbed on the surface and the strength of adsorption was were varied. The simulations were performed using the dynamic Monte Carlo method with local changes of chain conformations. The internal and local structures of a polymer layer were determined. The lateral diffusion and internal mobility of star‐branched chains were studied as a function of strength of adsorption and the chain length. The lateral diffusion and internal mobility of star‐branched chains were studied as a function of strength of adsorption and the chain length. It was shown that the behavior of grafted and weakly adsorbed chains was similar to that of a free three‐dimensional polymer, while the strongly adsorbed chains behave as a two‐dimensional system.