Abstract

Transverse collective excitations in 50-50 and 80-20 Lennard-Jones binary liquid mixtures are studied for different mass ratio of components R at fixed numerical densities. Increasing the mass ratio results in a growing difference between frequencies of shear waves and transverse optic modes. We report an increase in the propagation gap width for shear waves with mass ratio of components and compare it to the gap width expression, known from the transverse dynamics of simple liquids. A four-variable dynamic model of transverse dynamics in binary liquids with an account of cross correlations between total-mass and mass-concentration transverse current fluctuations is solved analytically in the long-wavelength region. An equation for the propagation gap of shear waves for binary liquids is reported and analyzed.

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