Abstract
Radical polymerization of dialkyl itaconates bearing cyclohexyl-based ester alkyl groups was examined kinetically. The propagation and termination rate constants were determined during the polymerization with dimethyl 2,2′-azobisisobutyrate in benzene at 60 ° by electron spin resonance spectroscopy. It was confirmed that the large kinetic orders with respect to the monomer in these polymerizations were related to the variable termination rate constant depending on the monomer concentration.
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