Production of iodine atoms by RF discharge decomposition of CF3I

Abstract

Generation of atomic iodine by dissociation of CF3I in a RF discharge was studied experimentally in a configuration ready for direct use of the method in an oxygen–iodine laser. The discharge was ignited between coaxial electrodes with a radial distance of 3.5 mm in a flowing mixture of 0.1–0.9 mmol s−1 of CF3I and 0.5–6 mmol s−1 of buffer gas (Ar, He) at a pressure of 2–3 kPa. The discharge stability was improved by different approaches so that the discharge could be operated up to a RF source limit of 500 W without sparking. The gas leaving the discharge was injected into the subsonic or supersonic flow of N2 and the concentration of generated atomic iodine and gas temperature were measured downstream of the injection. An inhomogeneous distribution of the produced iodine atoms among the injector exit holes was observed, which was attributed to a different gas residence time corresponding to each hole. The dissociation fraction was better with pure argon as a diluting gas than in the mixture of Ar–He, although the variation in the Ar flow rate had no significant effect on CF3I dissociation. The dissociation fraction calculated from the atomic iodine concentration measured several centimetres downstream of the injection was in the range 7–30% when the absorbed electric energy ranged from 200 to 4000 J per 1 mmol of CF3I. The corresponding values of the fraction of power spent on the dissociation decreased from 8% to 2% and the energy cost for one iodine atom increased from 30 to 130 eV. Due to a possible high rate of the atomic iodine loss by recombination after leaving the discharge, these values were considered as lower limits of those achieved in the discharge.