Abstract
Surface DBD (SDBD) discharge maintained in moist air in the immediate vicinity of the water surface is an effective source of reactive species for the production of plasma-activated water (PAW). In this work, we investigated the water activation process for two different DBD energization methods; i.e. using periodic HV pulses with nanosecond risetimes and amplitude-modulated HV AC. We combined UV–vis–NIR ICCD spectroscopy with electrical characteristics to determine the basic characteristics of SDBD microfilaments. Formation of N2O5/NO2/N2O/H2O2/NO2 −/NO3 − species was followed and the production yields of species generated in PAW (H2O2/NO2 −/NO3 −) were determined in a flow-through reactor under well-defined and stable discharge conditions. Both energization methods reached comparable energy efficiencies of nitrogen fixation in the range of 1–6 g kWh−1 with minimal concentrations of H2O2 (10 s μM). However, the AC-powered SDBD produced mainly NO3 − with minimal NO2 − (1/10 of NO3 −), while in the case of pulsed SDBD the better-balanced NO2 −/NO3 − ratio was achieved.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
