Production of High Purity Mg-X Rare Earth Binary Alloys Using Zr

Abstract

An Fe content lower than the tolerance limit is critical in controlling corrosion rates of Mg alloys. The possibility of reducing Fe below the tolerance in Mg melts was studied using Zr as a precipitating agent. The experiments were carried out on Mg-X binary alloys with rare-earths, X = Y, Ce, Gd, Nd, and La. The laboratory scale results show that Zr is effective in reducing the Fe content from the Mg melt for Mg-X binary alloys. Purification occurs by the precipitation from the melt of Fe rich precipitates, and the settling of the precipitates to the bottom of the melt. Any desired Fe content down to one wt ppm can in principle be achieved by appropriate melt treatment. The experimental results are discussed with respect to calculated phase diagrams.