Abstract

Lanthanum manganite (LaMnO3) nanofibers were synthesized using electrospinning technique. The size and uniformity of these nanofibers were optimized by varying PVP concentration. X-ray diffraction analysis revealed the formation of single phase LaMnO3 nanofibers (average diameter ~400nm) when the composite nanofibers were calcined at 600°C. M″ and Z″ spectroscopic plots of impedance spectroscopy data confirmed the presence of two distinct electro-active regions referred to as the grain and grain boundary regions. The activation energies of the grain and grain boundary regions were 0.27eV and 0.41eV, respectively; which suggested two different transport mechanisms in these fibers.

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