Abstract
AbstractSupported metal hydrides are key reactive intermediates in various catalytic processes, such as hydrogenation and dehydrogenation, but are often challenging to characterize spectroscopically. Here, deuterium solid state nuclear magnetic resonance spectroscopy is used to understand the structure of the corresponding silica‐supported zirconium hydrides after H/D exchange as an illustrative example of supported metal hydrides, which have been shown to display notable reactivity towards small molecules (e. g., CO2 and N2O) and to activate both C−H and C−C bonds, hence their use in to the conversion of hydrocarbons (alkanes, polyolefins etc.)
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