Prism coupling technique investigation of optical and thermo-optical properties of polyvinyl alcohol and polyvinyl alcohol/silica nanocomposite films

Abstract

In this paper, the optical and thermo-optical properties of polyvinyl alcohol (PVA) and polyvinyl alcohol/silica (PVA/SiO 2) nanocomposite films were characterized by using the prism coupler technique. The polymer films were deposited by solution casting method at room temperature. The refractive indices of TE polarization mode, nTE, of all samples were measured at 444 nm, 633 nm, 829 nm, and 1308 nm, respectively. The wavelength dependence of the refractive index is well described by Cauchy’s equation. The effect of polymer molecular weights and the concentration of silica nanoparticles on the optical properties of PVA films was also investigated and discussed. The refractive index of the PVA films was found to increase with molecular weight, whereas it decreases with the concentration of SiO 2 in PVA matrix. The variation of the refractive index of neat PVA and PVA/SiO 2 nanocomposite films with temperature in the range of 30 to 70 °C was determined. Both PVA and PVA/SiO 2 nanocomposites show negative thermo-optic coefficients (dn∕dT) of the order of 10−4 °C−1. Moreover, it was found that the addition of silica in the PVA affect thermo-optic coefficients of the films. The obtained results suggest that PVA is a material with tunable refractive indices and it is suitable for use in optical devices such as optical temperature sensors.