Primary Mg2Si phase and Mg2Si/α-Mg interface modified by Sn and Sb elements in a Mg-5Sn-2Si-1.5Al-1Zn-0.8Sb alloy

Abstract

The microstructure of primary Mg 2 Si and the interface of Mg 2 Si / α -Mg modified by Sn and Sb elements in an as-cast Mg-5Sn-2Si-1.5Al-1Zn-0.8Sb (wt.%) alloy were investigated. In the primary Mg 2 Si phase not only the Si atoms but also the Mg atoms could be substituted by Sn and Sb atoms, resulting in the slightly reduced lattice constant a of 0.627 nm. An OR of Mg 2 Si phase and α -Mg in the form of [ 001 ] Mg 2 Si ∥ [ 01 1 ¯ 1 ] α , ( 220 ) Mg 2 Si ∥ ( 0 1 ¯ 12 ) α was discovered. Between primary Mg 2 Si phase and α -Mg matrix two transitional nano-particle layers were formed. In the rim region of primary Mg 2 Si particle, Mg 2 Sn precipitates sizing from 5 nm to 50 nm were observed. Adjacent to the boundary of primary Mg 2 Si particle, luxuriant columnar crystals of primary Mg 2 Sn phase with width of about 25 nm and length of about 100 nm were distributed on the α -Mg matrix. The lattice constant of the Mg 2 Sn precipitate in primary Mg 2 Si particle was about 0.756 nm. Three ORs between Mg 2 Sn and Mg 2 Si were found, in which the Mg 2 Sn precipitates had strong bonding interfaces with Mg 2 Si phase. Three new minor ORs between Mg 2 Sn phase and α -Mg were found. The lattice constant of primary Mg 2 Sn phase was enlarged to 0.813 nm owing to the solution of Sn and Sb atoms. Primary Mg 2 Sn had edge-to-edge interfaces with α -Mg. Therefore, the primary Mg 2 Si particle and α -Mg were united and the interfacial adhesion was improved by the two nano-particles layers of Mg 2 Sn phase.