Pressure dependence of the rate constants for the electron/atom self-exchange between MII (cp2 and MIV) (cp)2 = X+ (M = ruthenium, osmium; X = bromide, iodide; cp = cyclopentadienide) as a function of solvent

Kim A Anderson,Harold W Dodgen,John P Hunt,Karl Kirchner,Scot Wherland

doi:10.1021/ic00038a054

Pressure dependence of the rate constants for the electron/atom self-exchange between MII (cp2 and MIV) (cp)2 = X+ (M = ruthenium, osmium; X = bromide, iodide; cp = cyclopentadienide) as a function of solvent

Kim A Anderson, Harold W Dodgen + Show 3 more

https://doi.org/10.1021/ic00038a054

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Journal: Inorganic Chemistry	Publication Date: Jun 1, 1992
Citations: 9

#NMR Line-broadening Techniques #Line-broadening Techniques + Show 3 more

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Abstract

The rate constants for the atom/electron self-exchange between Ru(cp) 2 and Ru(cp) 2 Br + (cp represents the cyclopentadienide anion), Ru(cp) 2 and Ru(cp) 2 I + , and Os(cp) 2 and Os(cp) 2 I + were measured by 1 H NMR line-broadening techniques as a function of pressure and solvent

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