Abstract
Measurements of N 2- and O 2-broadening of the rotational spectrum of CHF 2Cl have been performed up to frequencies of 686 GHz. The pressure broadening coefficients of eight different ( J+1) 2, J−1 ← J 1, J−1 rotational transitions have been measured and compared with semiclassical calculations. The observed decrease of the magnitude of pressure-broadening coefficients for J > 28 has been explained by considering line coupling effects which occur when the transitions ( J+1) 2, J−1 ← J 1, J−1 completely overlap the ( J+1) 3, J−1 ← J 2, J−1 ones.
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