Abstract
1. Polyvinylpyrrolidone stabilizes the reduced NaBH4 homogeneous Pd chlorodimethyl sulfoxide catalyst in hydrogenation and isomerization reactions. 2. A method has been developed for preparing and stabilizing Pd chlorodimethyl sulfoxide catalysts through treatment with N-polyvinylpyrrolidone. 3. The Pd complex, rather than the metallic palladium, is responsible for the activity of the supported catalyst in the reactions studied here.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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