Preparation of zwitterionic polymer and its application for dual-functional inhibition in deepwater drilling

Abstract

During deep-water drilling operations, due to the conditions with low temperature and high pressure in the wellbore, methane hydrate can be easily formed in the presence of methane and plug the wellbore. In addition, the deep-water sediments are dominated by clay-silty with weak cementation, so well instability may be occurred due to clay hydration. In order to inhibit hydrate formation and clay hydration in deepwater drilling, a zwitterionic polymer AADV was synthesized through quaternary copolymerization of AM/AMPS/DMDAAV/VAC. The hydrate inhibition performance of AADV was evaluated in a high-pressure reactor chamber, and the results showed that AADV can delay the hydrate formation time from 330 min in pure water to 2204 min, indicating an excellent inhibition effect of hydrate formation. Meanwhile, 1 % AADV can significantly reduce the linear swelling rate of the calcium-based bentonite to 3.69 % for 10 h and increase the rolling recovery rate to 94.7 %, suggesting an excellent inhibition effect on clay hydration. The mechanism of dual-functional inhibition of AADV was further analyzed. The zwitterionic group in AADV and the hydrophilic amide group can strongly adsorb the water molecules through a strong hydration effect and the hydrogen bonding effect, respectively, which contributes to destroy the water molecules cage structure, and thus to suppress the hydrate formation. Besides, AADV can effectively obstruct mass transfer of methane molecules by increasing the viscosity of the aqueous phase and absorbing on the hydrate surface, leading to hydrate formation inhibition. For the inhibition of clay hydration, the SEM and XRD results proved that AADC inhibits the clay hydration through the film-forming effect. In addition, the contact angle of Na-Bent/AADC composite reached to 55.68° when the polymer concentration increased to 2 %, suggesting that the hydrophobicity of Na-Bent surface can be enhanced after AADC treatment. AADV can wrap around clay particles and form hydrophobic film through adsorption and intercalation, preventing the intrusion of external fluids and inhibiting clay hydration.