Preparation of two different crystal structures of cerous phosphate as solid acid catalysts: their different catalytic performance in the aldol condensation reaction between furfural and acetone.

Abstract

Liquid fuel intermediates can be produced via aldol condensation reactions through furan aldehydes and ketones driven from biomass. It was found that cerous phosphate (CP) with two different crystal structures (hexagonal and monoclinic structure), which was tailored by different hydrothermal temperature (120 °C for the hexagonal structure and 180 °C for the monoclinic structure) and calcination temperature (900 °C for the monoclinic structure) as a solid acid catalyst, exhibit high catalytic performance in aldol condensation between furfural and acetone. The CP with hexagonal structure gave 89.1% conversion of furfural with 42% yield of 4-(2-furyl)-3-buten-2-one (FAc) and 17.5% of yield of 1,5-di-2-furanyl-1,4-pentadien-3-one (F2Ac), much higher than CP with monoclinic structure. However, both furfural conversion and aldol product yield increased from 82.3% to 96% and from 50.5% to 68.4%, respectively, for CP with the monoclinic structure after calcination owing to the higher amount of acid of catalyst after calcination but decreased continuously for CP with hexagonal structure after calcination because of its rapidly reduced BET surface area and total pore volume. The results indicated that calcination affects significantly the physical–chemical properties of CP catalysts, which influence subsequently the catalytic performance in the aldol condensation reaction. Recycling experiments showed that the catalytic performance after five number runs for CP with monoclinic structure after calcination was acceptable but was not ideal for CP with hexagonal structure owing to its poor hydrothermal stability.