Preparation of Primary Explosive by Self-assembly of Combustible and Oxidizing Agents under Acid.

Abstract

In order to further explore the effect of ligands on the performance of primary explosives and gain a deeper understanding of the coordination mechanism, we designed furan-2-carbohydrazide (FRCA), a ligand, by using oxygen-containing heterocycles and carbohydrazide. Then, FRCA and Cu(ClO4)2 were used to synthesize coordination compounds [Cu(FRCA)2(H2O)(ClO4)2]·CH3OH (ECCs-1·CH3OH) and Cu(FRCA)2(H2O)(ClO4)2 (ECCs-1). The structure of the ECCs-1 was confirmed by single-crystal X-ray diffraction, IR and EA characterization. Further experiments on ECCs-1 show that ECCs-1 has good thermal stability, but is sensitive to mechanical stimuli (impact sensitivity = IS = 8 J, friction sensitivity = FS = 20 N). The predicted value of the detonation parameter is DEXPLO5 = 6.6 km s-1, PEXPLO5 = 18.8 GPa, but the ignition test, laser test, and lead plate detonation experiment show that ECCs-1 has excellent detonation performance, which is very worthy of attention.