Abstract
The LiFePO4/C (LFP/C) composite as a cathode material for lithium-ion battery was synthesized by solid-state reaction under vacuum sintering condition (20–5Pa). The effects of vacuum sintering temperature and time on the phase composition, morphological structure, and electrochemical performance of LFP/C composite were investigated by X-ray diffraction, scanning electron microscopy, galvanostatic charge–discharge cycling test, and electrochemical impedance spectroscopy. The synthetic LFP/C composite possessed uniform particle-size distribution with porous architecture upon sintering at 650°C for 12h and thus exhibited the highest discharge capacity and best cycle performance. The complete decomposition of citric acid at a suitable temperature under vacuum condition resulted in the formation of porous structure. Compared with atmospheric argon sintering, vacuum sintering method led to the formation of porous architecture, the porous sample showed excellent cycle performance with less than 2% capacity loss after 80 cycles at 0.2C, and reached the discharge specific capacity of 87.6mAhg−1 at 10C rate, these are better than that of atmospheric argon sintering. The LFP/C composite prepared under vacuum sintering also reduced the optimum sintering temperature by nearly 100°C compared with that prepared under atmospheric argon sintering.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.