Preparation of phosphoric-modified aloe vera/chitosan aerogels and their efficient adsorption of U(VI).

Abstract

The efficient adsorption of radioactive elements from nuclear wastewater is an important research topic in the environmental field. The unique three-dimensional porous structure of aerogels has great potential in the field of adsorption. Phosphoric-modified aloe vera/chitosan aerogel (CS/AL-AP) was prepared from chitosan, phosphoric acid, and aloe powder by vacuum freeze-drying self-assembly. The maximum adsorption of uranyl ions by CS/AL-AP was found to be 322.34mg/g at pH 6, adsorption time of 120min, solid-to-liquid ratio of 0.125g/L, reaction temperature of 303K, and initial uranyl ion concentration of 50mg/L. The adsorption process is consistent with the Langmuir isotherm model and the quasi-secondary kinetic model, indicating that the adsorption process is monolayer adsorption. The type of adsorption is mainly chemisorption. FTIR and XPS analyses indicate that the adsorption of U(VI) by CS/AL-AP results from the combined action of coordination or chelation of amino, hydroxyl, and carboxyl groups. In addition, CS/AL-AP shows excellent adsorption capacity in the presence of complex co-existing ions. After five adsorption-desorption experiments, the adsorption capacity of CS/AL-AP for uranyl ions remained at a high level. It indicates that CS/AL-AP has good stability and recoverability. The results indicate that CS/AL-AP has excellent potential in the field of uranium removal.