Abstract

By Lewis acid catalysed allylic rearrangement reactions of various glycals with glycerol derivatives 2,3-unsaturated mono- and disaccharide glycosyl glycerol derivatives were obtained in good yields. A triglycosyl glycerol was successfully synthesized in a straightforward three step way from 3,4,6- tri- O-acetyl-1,5-anhydro-2-deoxy- d- arabino-hex-1-enitol.

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