Preparation of mixed Co and Cu oxides via thermal decomposition of their oxalates, and study of their catalytic properties

Abstract

Mixed oxides were prepared by the thermal decomposition of the oxalates of cobalt(II) and copper(II) coprecipitated from aqueous solution or made by mechanical mixing. The compositions and structures of the oxides were confirmed by means of TG and X-ray powder diffraction spectroscopy. The catalytic behaviour of the oxides obtained was studied by using the decomposition of H2O2 as a model reaction. The results were compared with those on the oxides produced from the thermal decomposition of mechanically mixed oxalates. The catalytic activities of the mixed oxides were found to be lower than that of pure cobalt oxide, but higher than that of copper oxide. This result was interpreted in terms of the relative standard reduction potential of the catalyst as compared with that of H2O2. The catalytic activity of the mixed oxides obtained from the coprecipitate was found to be lower than that of the oxides obtained from the mechanical mixture at the same temperature. As the temperature of preparation was increased, the catalytic activities of the oxides obtained decreased. This was attributed to the solid-solid interactions, which gave a new phase with lower catalytic activity than those of the interacting phases.