Preparation of magnetic Co–Fe layered double hydroxides and its adsorption properties for the removal of methyl orange

Abstract

In this study, Co–Fe layered double hydroxides are prepared by a hydrothermal method. The Co–Fe layered double hydroxides are used as an adsorbent for the investigation of the thermodynamic parameters and adsorption kinetics of methyl orange from aqueous solution. The results show that adsorption is affected by adsorbent dosage, adsorption time, and temperature. The characteristics of samples are investigated using X-ray powder diffraction, scanning electron microscopy, Fourier-transform infrared spectroscopy, and N2 adsorption–desorption isotherms. The adsorption saturation level of Co–Fe layered double hydroxides on methyl orange is studied, with the results showing that the maximum uptake capacity for methyl orange is 10.21 mg g−1 based on Co–Fe layered double hydroxides. The adsorption kinetics of methyl orange is consistent with the Temkin isotherm equation and quasi-secondary kinetic model. Furthermore, separation is easily accomplished under the action of an applied magnetic field. The prepared Co–Fe layered double hydroxides can be applied as an effective adsorbent for decontamination of anionic dyes in industrial effluents.