Preparation of macrodiolides via a common chiral building block. Total synthesis of (−)-pyrenophorin and (−)-pyrenophorol

Nobuo Machinaga,Chihiro Kibayashi

doi:10.1016/0040-4039(93)89027-n

Preparation of macrodiolides via a common chiral building block. Total synthesis of (−)-pyrenophorin and (−)-pyrenophorol

Nobuo Machinaga, Chihiro Kibayashi

https://doi.org/10.1016/0040-4039(93)89027-n

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Journal: Tetrahedron Letters	Publication Date: Jan 1, 1993
Citations: 37

Affiliation: National Institute of Technology, Tokyo College

#Common Chiral Building Block #Common Building Block #Chiral Building Block #Common Building #Chiral Building #Total Synthesis #Building Block

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Macrodiolides (−)-pyrenophorin and (−)-pyrenophorol have been synthesized utilizing a C2 symmetric (R,R)-diepoxide as a common enantiopure chiral building block.

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Preparation of macrodiolides via a common chiral building block. Total synthesis of (−)-pyrenophorin and (−)-pyrenophorol