Abstract
Liquid silicon-based carbon dots (CDs) with a photoluminescence quantum yield (PLQY) of 50% were prepared using N-[3-(trimethoxysilyl)propyl]ethylenediamine (DAMO), citric acid, and n-butylamine as raw materials. Firstly, the optimized characters have been determined, namely, the optimal DAMO, citric acid, and n-butylamine addition amounts of 1mL, 0.9g, and 1mL, a reaction time of 3h, and a reaction temperature of 160°C. Further research has confirmed that the increase in fluorescence intensity of CDs is mainly due to the introduction of DAMO, in which the two amino groups in DAMO play a major role. In addition, the Si-O-Si group generated by the hydrolysis of siloxane groups is connected to the surface of the CDs and forms a core-shell structure, which modifies the defects on the surface and enhances the fluorescence intensity of the CDs. Finally, luminescent solar concentrators (LSCs) based on liquid silicon-based CDs were assembled by spin coating. The obtained device has a transparency of up to 80% and an optical efficiency of 2.4%.
Published Version
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