Preparation of Highly Porous Graphitic Activated Carbon as Electrode Materials for Supercapacitors by Hydrothermal Pretreatment-Assisted Chemical Activation.

Abstract

The obstruction of traditional chemical activation lies in the addition of excessive catalysts to prepare the highly porous graphitic activated carbon (HPGAC), we propose the hydrothermal pretreatment-assisted chemical activation method to synthesize HPGAC as electrode materials using a small amount of Na-based catalysts (20 wt %). Hydrolysis accompanied by the strong depolymerization and reorganization of the coal framework is beneficial to the removal of different kinds of oxygen-containing structures (including cross-linking bonds, functional groups, and heterocycles) from lignite; thus, the deoxidization effect of hydrothermal carbonization (HTC) on hydrochar gradually strengthens with the increase in pretreatment temperature from 180 to 300 °C, resulting in the formation of a lot of disordered nanostructures and a smooth and compact surface. In the subsequent chemical activation stage, the microstructure of hydrochar is beneficial to the formation of a lot of graphene-like sheets and developed micropores even under a small amount of Na-based catalysts (20 wt %). The as-obtained C-HTC-300 with a highly ordered microstructure and a high specific surface area (SBET) of 1945.33 m2/g has an excellent electrochemical performance. Compared with a large consumption of catalyst for synthesizing HPGAC in traditional chemical activation, the hydrothermal pretreatment-assisted method meets the environmental protection and low-cost preparation requirements.