Preparation of highly dispersed SnO/TiO2 catalysts and their performances in catalyzing polyol ester.

Abstract

A series of stannous oxide supported on rutile titanium dioxide (SnO/TiO2) were prepared by a conventional incipient wetness impregnation method, and their performance as catalysts for fatty acid esterification reactions was investigated. The effects of Sn precursors (SnCl2·2H2O or SnC2O4), loading amounts (5-15%), and treating ambiences (air and N2) were explored. The optimized 10% SnO/TiO2-Cl with SnCl2·2H2O as the Sn precursor and thermal treatment in N2 showed the best esterification performance. Specifically, 10% SnO/TiO2-Cl catalyzed the esterification process of trimethylolpropane and n-octanoic acid with a conversion of 99.6% over 5 h at 160 °C, and 10% SnO/TiO2-Cl was efficient for six catalytic cycles. Based on the results of X-ray diffraction (XRD), Raman spectra, high-resolution transmission electron microscopy (HRTEM), infrared spectra of pyridine adsorption (Py-IR), and ammonia temperature programmed desorption (NH3-TPD), the improved catalytic performance is supposed to be attributable to the high dispersion of the Sn species on 10% SnO/TiO2-Cl as the moderate Lewis acid sites.