Abstract
AbstractSome polymer mixture systems become immiscible above a specific temperature, the so‐called lower critical solution temperature (LCST). In this work, the LCST behavior of a mixture of poly(ethylene oxide)‐block‐poly(propylene oxide)‐block‐poly(ethylene oxide) triblock copolymers and phenolic resin oligomers is observed, and the corresponding phase transition is exploited to develop a facile route to hierarchically structured carbon monoliths. Whereas evaporation‐induced self‐assembly generates hexagonal channels in the monoliths, an additional phase transition at the LCST leads to an ordered arrangement of isolated pores. The fabrication method involves annealing the gel‐phased mixture with polymeric microbeads in a 3D‐structured mold at the LCST, followed by thermosetting and a carbonization process. The LCST phase transition behavior is observed experimentally by in situ small‐angle X‐ray scattering, optical transparency measurements, differential scanning calorimetry, and infrared spectroscopy. The fundamental mechanism of the LCST phase transition is further investigated by atomistic molecular dynamics simulations.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
