Preparation of F, Cl and Nitrogen Doped TiO<sub>2</sub><sub> </sub>and their Photocatalytic Properties Research

Abstract

In the paper, sol-gel method has been used to make F-N, Cl-N co-doped TiO2 photocatalyst by the artificial zeolite as a carrier. The optimum doping and the best roasting temperature was found. The results showed that N, F co-doped photocatalyst can calcine at 400 °C, and when used in the best doping ratio as n (n-butyl titanate): n (ammonium chloride): n(N)= 1:0.01:0.012, its degradation rate can reach 92.4% in 3.5 hours. The N, Cl co-doped can calcine at 500 °C, and when used in the best doping ratio as n (n-butyl titanate): n (ammonium chloride):n(N) = 1:0.01:0.012 ,and the degradation rate of up to 88% in 3.5 hours. Scanning electron microscopy SEM and UV-visible spectrophotometry methods were used to analysis them,The results show that the experiment photocatalyst prepared in good condition. In the visible condition of the catalytic performance. The effection of F-N catalytic is better than Cl-N, and the degradation of methylene blue in 3.5 hours can reach 92.4%.