Preparation of Cu-Ce@γ-Al2O3 and Study on Catalytic Ozone Oxidation for the Treatment of RO Concentrate Water

Abstract

In this paper, a high-efficiency and stable Cu-Ce@γ-Al2O3 catalyst was prepared by taking the reverse osmosis (RO) concentrated water of a sewage treatment plant as the treatment object and activated alumina as the carrier. The preparation factors that affected the catalytic activity of Cu-Ce@γ-Al2O3 were investigated. SEM, EDS, XRD, BET, XRF, and XPS techniques were applied to characterize the catalyst. Optimal working conditions, and degradation mechanism of RO concentrated water were researched. In comparison with the ozone oxidation alone, the Cu-Ce@γ-Al2O3 catalytic ozonation has more reactive groups, significantly improving the treatment effect. Characterization results show that Cu and Ce are successfully supported on the surface of the activated alumina support and mainly exist in the form of oxides (e.g., CuO and CeO2). The loading of metal led to a larger specific surface area and pore volume. The repeated use had an insignificant effect on the peaks of Cu2p and Ce3d energy spectra and caused a small loss of active components. Under these conditions, the removal rate of COD from RO concentrated water by Cu-Ce@γ-Al2O3 catalyst was 85.2%. The stability and salt tolerance of Cu-Ce@γ-Al2O3 catalysts were investigated by catalyst wear rate and repeated use times, respectively. The degradation of organic matter and residual tryptophan-like organic compounds were observed through UV absorption spectroscopy and 3D-EEM. Hydroxyl radicals participated in organic pollutants degradation. Finally, a multi-level-fuzzy analysis evaluation model was developed to quantitatively assess the catalytic ozone oxidation system of the Cu-Ce @γ-Al2O3 catalyst for the treatment of RO concentrated water.