Preparation of Cu–Ni alloy nanocrystallites in water-in-oil microemulsions

Abstract

The well-mixed copper–nickel nanoparticles were prepared when the molar ratio of Cu 2+ to Ni 2+ was 1:1 by simultaneous reduction of CuSO 4 and NiCl 2 with hydrazine in the microemulsion of SDS/ n-butanol/ n-heptane/water at 70 °C, and was characterized by TEM, ED, TGA, EDS, and XRD. ED analysis and XRD patterns suggest the formation of the homogeneous alloy structure in the bimetallic nanoparticles. Average size of the sample calculated from the full width at medium height of peak 111 in the XRD patterns using Scherrer formula is 5.53 nm. TEM photographs show a narrow distribution of Cu–Ni nanoparticles that essentially are monodispersed and the mean diameter is 12 nm. The results indicate that the composition and size of alloy nanoparticles depend on the mole ratio of H 2O to SDS, the method of addition of Cu 2+ and Ni 2+, and the mole ratio of Cu 2+ and Ni 2+ in the initial precursor solution.