Preparation of biochar by mango peel and its adsorption characteristics of Cd(ii) in solution.

Abstract

Biochars were prepared by pyrolyzing mango peel waste at 300, 400, 500, 600 and 700 °C. Various characterizations were carried out to explore the effect of pyrolysis temperature on the biochars. The data indicated that the physical and chemical properties of biochar such as pH, element ratio, specific surface area and functional groups changed with the increase of pyrolysis temperature. The yield and contents of hydrogen, nitrogen and oxygen decreased, while contents of the ash and carbon, pH and specific surface area of the biochars increased. In addition, the molar ratios of H/C, O/C and (O + N)/C decreased. In this study, batch adsorption experiments for Cd(ii) adsorption were performed with initial Cd(ii) concentrations of 10–300 mg L−1, contact times of 0–2880 min, various pH (2–8) and biochar dose (1–20 g L−1). Langmuir isotherm and pseudo-second-order kinetics models were better fits than other models, suggesting the dominant adsorption of mango peel biochars is via monolayer adsorption. Biochar derived at 500 °C was found to have the highest adsorption capacity of 13.28 mg g−1 among all biochars and the adsorption efficiency was still 67.7% of the initial adsorption capacity after desorption for 4 times. Based on adsorption kinetics and isotherm analysis in combination with EDS, FTIR and XRD analysis, it was concluded that cation exchange, complexation with surface functional groups and precipitation with minerals were the dominant mechanisms responsible for Cd adsorption by mango peel biochar. The study suggested that mango peel can be recycled to biochars and can be used as a low-cost adsorbent for Cd(ii) removal from wastewater.