Abstract
In this paper, the waste polyethylene terephthalate (PET) was glycolysed by trimethylolpropane with zinc acetate as catalyst. The effects of different content glycolysis product of waste PET on the appearance, viscosity, particle size and molecular weight of autoxidative water-reducible alkyd resins and the corresponding film adhesion, flexibility, impact resistance, gloss, hardness and chemical resistance were studied. Meanwhile, experimental results were compared with commercial water-reducible alkyd and water-reducible alkyd without the glycolysis product of waste PET. The results show that the maximum concentration of PET in autoxidative water-reducible alkyd resins can reach 8.5 wt%, and the molecular weight, particle size and viscosity of water-reducible alkyd resin do not change much with the increase of PET concentration. The introduction of PET resulted in the viscosity of water-reducible alkyd resins being greater than that of water-reducible alkyd resin without PET; this is mainly because PET contains harder terephthalic acid monomer units. However, the particle size of water-reducible alkyd resins with waste PET is significantly lower than that of the water-reducible alkyd resin without PET; this is due to PET-free water-reducible alkyd resin containing more pentaerythritol with greater steric hindrance. In addition, the hardness of the water-reducible alkyd resin paint film (PET content is 8.5%) reaches 1H, which is higher than the hardness (HB) of the water-reducible alkyd resin paint film without PET and the commercial alkyd resin paint film, while the physical properties and chemical resistance of the former are comparable to those of the latter two kinds of paint films. Therefore, the use of waste PET in water-borne coatings systems not only reduces the cost of coatings, but also opens up a new market for recycled PET, which may contribute a promising method for management of waste PET.
Highlights
Polyethylene terephthalate (PET) possesses excellent transparency, stability and plasticity [1], so it is widely used in food, medical treatment, industry and other fields [1,2]
Owing to part of the polyols and polyacids of the alkyd resins being replaced by the glycolysed products of waste PET, the oil length in this experiment was between 41.60% and 39.91%
The waste PET was glycolysed by trimethylolpropane with zinc acetate as catalyst
Summary
Polyethylene terephthalate (PET) possesses excellent transparency, stability and plasticity [1], so it is widely used in food, medical treatment, industry and other fields [1,2]. Waste PET is not decomposed in natural conditions, which wastes a lot of space and results in serious environmental pollution [1,3]. The recycling of waste PET bottles solves the problem of solid waste disposal and recycling, and its depolymerized products can be used in coating, textile, ink and other industrial fields [1,2,4]. The waste PET materials are treated in the following ways: landfill disposal, mechanical recycling, chemical recycling and incineration [1,5]. Chemical recycling of waste PET is one of the most efficient methods for recycling [2,4]. Chemical recovery can decompose polymers into oligomers and monomers, and oligomers and monomers can be used in new industrial fields, which is not dependent on oil resources and crude oil [1,6]
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