Abstract
7,8-Diazaphencyclone 7 is used as a delivery reagent to fuse 1,10-phenanthroline groups onto alkenic centres of rigid spacer molecular racks (molracs); molrac alkenes containing redox-active donor–acceptor chromophores yield molrac diads whose metal complexes, e.g. 26, are suitable for mechanistic studies involving intramolecular electron transfer.
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