Abstract
The β-diketone complexes of vanadium(IV), VO(dik) 2 (where dik ≡; btfac, tfac, ttfac, acac, bzac and bzbz) have been prepared either by the reaction of vanadium pentoxide with the appropriate ligand in toluene under reflux for 24 h or by the reaction of a warm aqueous or ethanolic solution of vanadium sulphate with the ligand. The oxovanadium(IV) complexes react with sulphur oxide dichloride and dibromide and phosphorus pentachloride to form dihalovanadium(IV) diketonate complexes. These compounds have been characterized by elemental analysis, melting point measurements, IR and Raman spectra, magnetic susceptibility measurements, electron spin resonance (ESR) and mass spectral studies and X-ray powder diffraction.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
