Abstract

This study proposes the use of a ZnO-nanowire (ZnO-NW)-based heterojunction structure for applications of nano optoelectronic sensors and photovoltaic devices. Nano heterojunctions (NHJs) were formed via e-beam deposition of ptype nickel oxide (NiO) onto the vertical-aligned ZnO-NWs grown by hydro-thermal growth method. The dark J-V curve shows that the prepared NiO/ZnO-NWs NHJ has a diode-like behavior with a forward threshold voltage (V<sub>th</sub>) of 1.2 V and a leakage current (J<sub>r</sub> at -1V) of 0.02 &mu;A/cm<sup>2</sup>, respectively. It also exhibits a superior response to UV (366 nm) and AM 1.5G light illuminations. The V<sub>th</sub> and the photocurrents (i.e., J<sub>r</sub> at -1V) under UV (366 nm @ 6 mW/cm<sup>2</sup>) and AM 1.5G light were 0.7 V/0.06 &mu;A/cm<sup>2</sup> and 0.5 V/ 3.2 &mu;A/cm<sup>2</sup>, respectively, revealing an increase in the diode current of about 3&times; and 160&times;, respectively.

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