Abstract

Phosphorus scale inhibitor is a kind of agent which can disperse insoluble inorganic salts in water, prevent or interfere with the precipitation and scaling of insoluble inorganic salts on metal surface, and maintain better heat transfer effect of metal equipment. Sodium triethylenetetramine hexamethylphosphonate (TETHMPS) and tetraethylenepentamine heptagon methylene phosphonic (TEPHMPS) were prepared by one-step synthesis method. The effects of temperature, concentration and mixing ratio on scale inhibition were investigated. The results showed that as the concentration of TETHMPS and TEPHMPS increases, the scale inhibition rate increases. At the same temperature, compared with TETHMPS, TEPHMPS has better scale inhibition performance, and the maximum scale inhibition rate can reach 93.59%. The scale inhibition rate of the synthesized scale inhibitor at 80 °C is better than that at 60 °C. The scale inhibition performance of the compound scale inhibitor is better than that of the single scale inhibitor, showing an ideal synergistic effect. When the concentration is 60 mg/L, the scale inhibition rate of TETHMPS is 94.26%, TEPHMPS is 94.55%, and the scale inhibition rate is above 91%.

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