Abstract
Ruddlesden-Popper phases La1.5Pr0.5NiO4 (LPN) and La1.5Pr0.5Ni0.9Cu0.1O4 (LPNC) are synthesized by a modified complexing sol-gel process as cathode for intermediate temperature solid oxide fuel cells (IT-SOFCs). The X-ray powder diffraction characterization confirms the formation of pure single-phase of cathodes and the favorable chemical compatibility with the Sm0.2Ce0.8O1.9 (SDC) electrolyte. The thermal expansion coefficients (TECs) of the LPN and LPNC are 15.0 × 10−6 K−1 and 14.5 × 10−6 K−1, respectively. The electrical conductivities are 61 and 72 S. cm−1 for LPN and LPNC at 400 °C, respectively. The minimum polarization resistance (RP) obtained on SDC electrolyte is 0.047 Ω cm2 at 800 °C for LPNC cathode. The peak power density is 567 mW cm−2 for LPNC at 800 °C while 504 mW cm−2 for LPN in the same conditions. All the studies involved in this work show potential use of the LPNC cathode for IT-SOFCs.
Published Version
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