Preparation and electrical properties of fully organic copolymer-based composite films

Abstract

Polymer-based energy storage media are widely used in electrical and electronic applications due to their high power density and excellent charge and discharge efficiency. In this paper, thermoplastic polyurethane elastomer (TPU) organic fillers were doped with polyetherimide (PEI) by the solution blending method to prepare PEI composite films with excellent energy storage properties. The effects of different TPU contents on the dielectric properties, leakage current density, and energy storage performance of the composite films were explored. The results showed that the flexible TPU fillers, which could improve the inter-chain interactions and spatial structure of PEI, reduced the chain spacing of the polymer, effectively hindered the input of charge carriers, and mitigated the electric field distortion, thus improving the insulation and dielectric properties of PEI. When the mass fraction of the added TPU elastomer reaches 0.75%, the energy storage density of the composite film reaches 11.51 J/cm3, which is 2.88 J/cm3 higher than that of the pure polyetherimide, while maintaining a high charge/discharge efficiency (87.32%), and the energy storage performance has been significantly improved under an applied electric field strength of 600 MV/m. The results show that the composite film is more efficient than the pure polyetherimide, and the energy storage performance has been significantly improved.